Endorsement H

Hazardous Materials CDL Practice Test

50 real exam-style questions covering Hazard classes 1–9, Placards and shipping papers, Loading and segregation, Emergency response and the ERG and more. Instant scoring, full written explanations, free to use.

About the Hazardous Materials exam

The Hazardous Materials knowledge exam qualifies a CDL holder to transport hazardous materials in quantities that require federal placarding, after both a written exam and a TSA threat assessment. Drivers seeking the H endorsement on a Class A or B commercial driver's license must demonstrate competency on a written test administered by their state driver licensing agency, drawn from the federal model curriculum published in the AAMVA Commercial Driver License Manual.

The exam covers material that, in practice, falls into a handful of focus areas: Hazard classes 1–9, Placards and shipping papers, Loading and segregation, Emergency response and the ERG, Driving and parking rules, Tunnel and route restrictions, Security threat awareness. Each subject map back to a specific section of the federal CDL manual, and most state versions of the test follow the same structure with minor wording variations. Drivers should expect multiple-choice questions that emphasize safe operating procedures, equipment inspection, defensive driving behavior, and a working knowledge of federal regulations.

Eligibility for testing requires a passing General Knowledge score, a TSA Security Threat Assessment, and an additional state hazmat application fee. Once you pass the knowledge exam, the endorsement is recorded on your CDL after you also pass any required skills test components. The endorsement carries forward as long as you renew your CDL on schedule and meet the medical certification requirements set by the Federal Motor Carrier Safety Administration.

Study tips that actually move the score

Veteran instructors at CDL training schools consistently recommend a study plan that pairs your state's official handbook with daily practice testing on the Hazardous Materials content. The questions on the actual exam tend to test recognition rather than recall, which means repeated exposure to the question format matters as much as memorizing facts.

  1. Memorize the nine UN hazard class numbers and what each represents.
  2. Know when placards are required: 1,000 lbs aggregate gross weight in most cases; any quantity for Table 1 materials.
  3. Be able to read the segregation table and identify which materials may not be loaded together.
  4. Understand the role of the Emergency Response Guidebook and where it must be kept.
  5. Memorize the prohibition on smoking near placarded loads and the brake-set requirement when loading or unloading.

If you find yourself missing the same questions repeatedly, slow down and read the explanation rather than retaking the quiz. The Hazardous Materials exam is designed so that an attentive driver who has read the manual once can pass on the first attempt; most failures come from rushing or from skipping the manual section that the question is testing.

Plan to spend roughly two to three hours studying for every hour you expect the test to take. The Hazardous Materials written exam itself usually runs twenty to forty questions; budget at least six to ten hours of focused review across multiple sittings rather than one long cram session.

Hazardous Materials · Practice Quiz

Read each question carefully, choose the best answer, and review the explanation below before moving on.

  1. Question 1

    Hazmat placards are designed to:

    • A Warn others of the hazard class of the cargo Correct answer
    • B Show the price of the cargo
    • C Show the driver's license number
    • D Indicate the destination
    Show explanation

    Placards are diamond-shaped warning signs that communicate hazard class to other drivers, emergency responders, and inspectors.

    Topic: Placards · Permalink to this question

  2. Question 2

    Placards must be displayed on:

    • A The driver's door
    • B Only the front
    • C Only the rear
    • D All four sides of the vehicle Correct answer
    Show explanation

    Federal regulation requires placards on all four sides of the vehicle so the hazard is visible from any approach.

    Topic: Placards · Permalink to this question

  3. Question 3

    Class 1 hazardous materials are:

    • A Corrosives
    • B Explosives Correct answer
    • C Radioactive materials
    • D Flammable liquids
    Show explanation

    Class 1 covers explosives, divided into divisions 1.1 through 1.6 based on hazard severity.

    Topic: Hazard classes · Permalink to this question

  4. Question 4

    Class 2 hazardous materials are:

    • A Explosives
    • B Corrosives
    • C Solids
    • D Gases Correct answer
    Show explanation

    Class 2 covers gases, including flammable, non-flammable, toxic, and oxygen.

    Topic: Hazard classes · Permalink to this question

  5. Question 5

    Class 3 hazardous materials are:

    • A Flammable liquids Correct answer
    • B Radioactive materials
    • C Explosives
    • D Solids
    Show explanation

    Class 3 covers flammable and combustible liquids such as gasoline, diesel, and many chemicals.

    Topic: Hazard classes · Permalink to this question

  6. Question 6

    Class 7 hazardous materials are:

    • A Flammable liquids
    • B Corrosives
    • C Explosives
    • D Radioactive materials Correct answer
    Show explanation

    Class 7 covers radioactive materials, with strict packaging, shielding, and labeling requirements.

    Topic: Hazard classes · Permalink to this question

  7. Question 7

    Class 8 hazardous materials are:

    • A Solids
    • B Gases
    • C Corrosives Correct answer
    • D Explosives
    Show explanation

    Class 8 covers corrosive materials such as battery acid and many industrial chemicals.

    Topic: Hazard classes · Permalink to this question

  8. Question 8

    Class 9 hazardous materials are:

    • A Miscellaneous dangerous goods that don't fit other classes Correct answer
    • B Radioactive
    • C Solids
    • D Explosives
    Show explanation

    Class 9 is a catch-all for materials presenting a hazard during transport but not meeting criteria for classes 1-8.

    Topic: Hazard classes · Permalink to this question

  9. Question 9

    Shipping papers for hazmat must be:

    • A Stored at the office
    • B Mailed in advance
    • C In the trailer
    • D Within reach of the driver and clearly distinguishable from other paperwork Correct answer
    Show explanation

    Shipping papers must be on the driver's seat, in a holder mounted on the inside of the driver's door, or in reach when the seat belt is fastened — and clearly identifiable.

    Topic: Shipping papers · Permalink to this question

  10. Question 10

    When stopped, hazmat shipping papers should be:

    • A Mailed to dispatch
    • B Within reach when in the cab; on the seat or in the door pouch when out of the cab Correct answer
    • C Posted on the back of the trailer
    • D Locked in the trunk
    Show explanation

    When the driver leaves the cab, papers go on the driver's seat or in the door pouch — visible to first responders if the driver is incapacitated.

    Topic: Shipping papers · Permalink to this question

  11. Question 11

    A hazmat shipping paper must include:

    • A Only the consignee
    • B Only the weight
    • C Just the destination
    • D Proper shipping name, hazard class, ID number, packing group, and quantity Correct answer
    Show explanation

    Shipping papers must include the proper shipping name, hazard class/division, UN/NA identification number, packing group, and total quantity.

    Topic: Shipping papers · Permalink to this question

  12. Question 12

    The Emergency Response Guide (ERG) helps:

    • A First responders identify and respond to hazmat incidents Correct answer
    • B Dispatchers schedule loads
    • C Mechanics service the truck
    • D Drivers find rest stops
    Show explanation

    The ERG provides initial response guidance based on the UN ID number on the placards or shipping papers. Carry the current edition.

    Topic: Shipping papers · Permalink to this question

  13. Question 13

    When loading hazmat, you should:

    • A Leave the engine running
    • B Idle at high RPM
    • C Set the parking brakes and chock wheels if necessary Correct answer
    • D Disconnect the trailer
    Show explanation

    Set parking brakes during loading/unloading to prevent the truck from rolling and to allow the loader to work safely.

    Topic: Loading · Permalink to this question

  14. Question 14

    Smoking near a placarded vehicle is:

    • A Allowed if it's a smoke break
    • B Allowed in tunnels
    • C Prohibited within 25 feet of the vehicle Correct answer
    • D Allowed if you are downwind
    Show explanation

    Federal regulation prohibits smoking within 25 feet of a placarded vehicle, fueling area, or hazmat storage facility.

    Topic: Loading · Permalink to this question

  15. Question 15

    During loading and unloading of hazmat:

    • A Equipment can run unattended
    • B The driver or designee must be in attendance, watching for problems Correct answer
    • C Load alone is acceptable
    • D The driver may leave the area
    Show explanation

    A trained person must be in attendance whenever hazmat is being loaded or unloaded.

    Topic: Loading · Permalink to this question

  16. Question 16

    The Segregation Table identifies materials that:

    • A Cannot be loaded, transported, or stored together Correct answer
    • B Require special licenses
    • C Are taxed at higher rates
    • D Have higher insurance
    Show explanation

    The Segregation Table at 49 CFR §177.848 lists incompatible material combinations that may not share the same vehicle, container, or storage area.

    Topic: Segregation · Permalink to this question

  17. Question 17

    Class 1 explosives must NOT be loaded with:

    • A No other materials
    • B Only Class 8
    • C Only Class 9
    • D Most other hazmat classes (with limited exceptions) Correct answer
    Show explanation

    Explosives have stringent segregation requirements; the Segregation Table prohibits most combinations.

    Topic: Segregation · Permalink to this question

  18. Question 18

    When driving a placarded vehicle, you must avoid:

    • A Rest areas
    • B Truck stops
    • C All highways
    • D Tunnels and bridges where prohibited Correct answer
    Show explanation

    Many tunnels and some bridges restrict hazmat. Check route restrictions in advance and follow alternate routes when required.

    Topic: Driving rules · Permalink to this question

  19. Question 19

    A placarded hazmat vehicle must stop before crossing:

    • A Every intersection
    • B All bridges
    • C Railroad tracks (with very few exceptions) Correct answer
    • D Every truck stop
    Show explanation

    Federal regulation requires placarded hazmat vehicles to stop 15-50 feet before all railroad tracks unless specifically exempted (e.g., shunting tracks).

    Topic: Driving rules · Permalink to this question

  20. Question 20

    When approaching a railroad crossing in a placarded vehicle, you must stop:

    • A Within 50 feet but not closer than 15 feet of the nearest rail Correct answer
    • B Anywhere within sight
    • C Right on the tracks
    • D 100 feet before
    Show explanation

    The required stop distance is 15 to 50 feet from the nearest rail, allowing you to see and hear approaching trains while remaining clear of the tracks.

    Topic: Driving rules · Permalink to this question

  21. Question 21

    Refueling a hazmat vehicle while the engine is running is:

    • A Allowed only at company terminals
    • B Always required
    • C Prohibited Correct answer
    • D Allowed at low RPM
    Show explanation

    Engine must be shut off during refueling. A person must be in control of the fueling process at all times.

    Topic: Driving rules · Permalink to this question

  22. Question 22

    A placarded hazmat vehicle should be parked:

    • A At least 5 feet from the traveled portion of the road, with attendance or specific exceptions Correct answer
    • B On private property without permission
    • C In residential driveways
    • D On the shoulder of any road
    Show explanation

    Parking rules vary; generally, placarded vehicles must be at least 5 feet from the road, with an attendant unless certain exceptions apply (e.g., safe haven for explosives).

    Topic: Parking · Permalink to this question

  23. Question 23

    Class 1 explosives may not be parked within:

    • A 1000 feet only
    • B 10 feet only
    • C 300 feet of bridges, tunnels, dwellings, or crowded places Correct answer
    • D 50 feet only
    Show explanation

    Explosive loads carry the strictest parking distance requirements: 300 feet from bridges, tunnels, dwellings, and crowded places.

    Topic: Parking · Permalink to this question

  24. Question 24

    Hazmat drivers must check tires:

    • A Once per month
    • B Once per week
    • C At the start of each trip and each time the vehicle is parked Correct answer
    • D Only at fueling
    Show explanation

    Tire checks at start of trip and at each parking are required for placarded vehicles. Hot tires can be the first sign of a brake or wheel issue that could ignite a load.

    Topic: Tires · Permalink to this question

  25. Question 25

    If you have a hazmat fire, you should:

    • A Use the parking brake
    • B Try to drive away
    • C Use the proper extinguisher type for the material; if unsure or the fire is too large, evacuate and call 911 Correct answer
    • D Always use water
    Show explanation

    Wrong extinguisher type can spread the fire (e.g., water on burning lithium). Refer to the ERG and prioritize personal safety.

    Topic: Emergency · Permalink to this question

  26. Question 26

    If hazmat begins to leak, you should:

    • A Stop in a safe location, isolate the area, notify authorities, and stay upwind Correct answer
    • B Contact dispatch only
    • C Try to plug the leak with rags
    • D Continue driving
    Show explanation

    Stop, isolate, notify, stay upwind. Refer to the ERG for material-specific guidance.

    Topic: Emergency · Permalink to this question

  27. Question 27

    After a hazmat incident, you must report to:

    • A No one
    • B Only the local mechanic
    • C Your employer and, in serious cases, the National Response Center Correct answer
    • D Only your friends
    Show explanation

    Carriers must notify their company and may be required to notify the NRC at 1-800-424-8802 for spills meeting reporting thresholds.

    Topic: Emergency · Permalink to this question

  28. Question 28

    The TSA Security Threat Assessment for Hazmat checks:

    • A Credit history
    • B Driving record only
    • C Criminal history, immigration status, and intelligence databases Correct answer
    • D Health history
    Show explanation

    TSA reviews the applicant's criminal, immigration, and intelligence background as a condition for the H endorsement.

    Topic: Security · Permalink to this question

  29. Question 29

    A Hazmat endorsement must be renewed every:

    • A 5 years (with a fresh TSA assessment) Correct answer
    • B 10 years
    • C 15 years
    • D 2 years
    Show explanation

    H endorsement renewals are on a 5-year cycle, with each renewal requiring a fresh TSA threat assessment.

    Topic: Security · Permalink to this question

  30. Question 30

    During hazmat security awareness, drivers should:

    • A Ignore strangers
    • B Allow anyone to handle the load
    • C Skip routine inspections
    • D Watch for suspicious behavior and unusual changes in routine Correct answer
    Show explanation

    Security awareness training emphasizes vigilance for unusual activity, secure parking, and verification of identities of anyone interacting with the load.

    Topic: Security · Permalink to this question

  31. Question 31

    A vehicle with 1,001 lbs or more of hazmat:

    • A Generally requires placards (with material-specific exceptions) Correct answer
    • B Requires placards only at night
    • C Never requires placards
    • D Requires placards only on highways
    Show explanation

    The 1,001-lb aggregate weight threshold triggers placarding for most materials. "Table 1" materials (explosives, poison gases, etc.) require placards in any quantity.

    Topic: Placards · Permalink to this question

  32. Question 32

    A residue tank that previously held hazmat:

    • A Uses only Class 9 placards
    • B Never needs placards
    • C Must continue to display the previous placards until properly purged Correct answer
    • D Removes placards immediately after unloading
    Show explanation

    Empty tanks containing hazmat residue must continue to display placards until cleaned and purged of vapor.

    Topic: Placards · Permalink to this question

  33. Question 33

    A driver may refuse to transport a hazmat shipment if:

    • A The destination is far
    • B The driver is tired
    • C The shipment is improperly packaged, marked, labeled, or documented Correct answer
    • D The fuel is low
    Show explanation

    Driver responsibility includes refusing improperly prepared shipments — accepting them transfers liability and creates safety risk.

    Topic: Driver responsibility · Permalink to this question

  34. Question 34

    Before driving a hazmat load, the driver must verify:

    • A Only the destination
    • B That packaging is intact, papers are correct, placards are right, and the load is properly secured Correct answer
    • C Only the fuel
    • D Only the route
    Show explanation

    Pre-trip verification of packaging, papers, placards, and securement is the driver's legal responsibility.

    Topic: Driver responsibility · Permalink to this question

  35. Question 35

    A "label" on a hazmat package is:

    • A The shipping address
    • B A smaller version of the placard, applied to packages Correct answer
    • C The truck number
    • D The fuel type
    Show explanation

    Labels are diamond-shaped, smaller than placards, applied to individual packages to communicate hazard class.

    Topic: Marking and labeling · Permalink to this question

  36. Question 36

    The proper shipping name on a package must:

    • A Be in any language
    • B Match the name on the shipping papers exactly Correct answer
    • C Be only on the bill of lading
    • D Be optional
    Show explanation

    Consistency between package marking and shipping papers is essential for first responders to identify the material.

    Topic: Marking and labeling · Permalink to this question

  37. Question 37

    A "designated route" for hazmat is:

    • A A toll road
    • B A route that local or state authorities require placarded loads to follow Correct answer
    • C A scenic route
    • D The shortest route
    Show explanation

    States and municipalities can designate specific routes for placarded hazmat loads, often avoiding tunnels, bridges, and dense populations.

    Topic: Routing · Permalink to this question

  38. Question 38

    When in doubt about a hazmat route, you should:

    • A Consult your dispatcher or carrier safety manager Correct answer
    • B Drive the shortest path
    • C Use the GPS only
    • D Follow another truck
    Show explanation

    Dispatchers, safety managers, and the FMCSA hazmat routing tool can confirm legal routing for your load.

    Topic: Routing · Permalink to this question

  39. Question 39

    When unloading at a customer site, the driver should:

    • A Walk away
    • B Leave engine running
    • C Leave keys in the ignition
    • D Set parking brake, chock wheels, and follow the consignee's safety procedures Correct answer
    Show explanation

    Standard practice: secure the truck, follow the consignee's safety rules, and supervise unloading.

    Topic: Loading dock · Permalink to this question

  40. Question 40

    Cargo manifests for hazmat:

    • A Are sent by mail only
    • B Are filed weekly
    • C Are required and must be accurate Correct answer
    • D Are optional
    Show explanation

    Accurate manifests are required for every hazmat shipment to ensure first responders can identify materials in an incident.

    Topic: Documentation · Permalink to this question

  41. Question 41

    You must inform receivers if:

    • A You stopped for fuel
    • B Hazmat has leaked or been damaged in transit Correct answer
    • C The dispatcher called you
    • D You took a different route
    Show explanation

    Notify receivers immediately if any hazmat package is damaged or leaks during transit.

    Topic: Driver duties · Permalink to this question

  42. Question 42

    When transporting hazmat, communicating your presence and load condition is:

    • A Optional
    • B Essential — be specific about the material involved if there is a problem Correct answer
    • C Only if asked
    • D Done only at the destination
    Show explanation

    Clear communication about material identity is essential to first responders during any incident.

    Topic: Communications · Permalink to this question

  43. Question 43

    Division 6.1 materials are:

    • A Explosives
    • B Corrosives
    • C Poisons (toxic by inhalation, oral, or dermal exposure) Correct answer
    • D Gases
    Show explanation

    Division 6.1 covers materials that are toxic to humans through inhalation, ingestion, or skin contact.

    Topic: Hazard classes · Permalink to this question

  44. Question 44

    Division 6.2 materials are:

    • A Corrosives
    • B Infectious substances (biohazards) Correct answer
    • C Explosives
    • D Compressed gases
    Show explanation

    Division 6.2 covers infectious substances such as medical waste, cultures, and clinical specimens.

    Topic: Hazard classes · Permalink to this question

  45. Question 45

    Class 5 includes:

    • A Solids only
    • B Corrosives only
    • C Gases only
    • D Oxidizers and organic peroxides Correct answer
    Show explanation

    Class 5 has two divisions: 5.1 oxidizers and 5.2 organic peroxides — both promote combustion of other materials.

    Topic: Hazard classes · Permalink to this question

  46. Question 46

    Class 4 includes:

    • A Gases
    • B Flammable solids, spontaneously combustible materials, and dangerous-when-wet materials Correct answer
    • C Explosives
    • D Liquids
    Show explanation

    Class 4 has three divisions: 4.1 flammable solids, 4.2 spontaneously combustible, and 4.3 dangerous when wet.

    Topic: Hazard classes · Permalink to this question

  47. Question 47

    Floor-loading rules require that:

    • A Hazmat be loaded so it does not shift, fall, or contact other incompatible materials Correct answer
    • B Hazmat be loaded first only
    • C Hazmat be loaded last only
    • D Hazmat be loose
    Show explanation

    Loading must prevent shift, fall, or incompatible contact. Use blocking, bracing, dunnage, or load bars as needed.

    Topic: Loading · Permalink to this question

  48. Question 48

    Many tunnels prohibit:

    • A Cars only
    • B All trucks
    • C Buses only
    • D Vehicles carrying placarded hazmat Correct answer
    Show explanation

    Tunnel prohibitions vary; many tunnels prohibit placarded hazmat or specific divisions (especially explosives and flammable gases).

    Topic: Tunnels · Permalink to this question

  49. Question 49

    Mileage records for hazmat trips must be:

    • A Sent to the customer
    • B Maintained as required by federal regulation Correct answer
    • C Posted on social media
    • D Optional
    Show explanation

    Hazmat carriers maintain mileage records and other documentation as required for safety and compliance auditing.

    Topic: Driver duties · Permalink to this question

  50. Question 50

    In an emergency, you should give first responders:

    • A Your CDL
    • B The keys to the cab
    • C Your phone
    • D Shipping papers, the ERG, and any safety information you have Correct answer
    Show explanation

    Provide shipping papers and the ERG. These give first responders critical information to manage the incident safely.

    Topic: Communications · Permalink to this question